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40d:Bauxite
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Bauxite is the only stone, apart from Raw adamantine, which is suitable for the construction of mechanisms to be used in floodgates which will come into contact with magma. Unfortunately bauxite can be found only in sedimentary layers, which are rare around volcanoes (but not near magma pipes in general). However, you can usually trade for Bauxite stones with the Dwarven caravans (this is determined by availability in your home civilization). They're not expensive, and you should get enough to make any number of bauxite mechanisms you need. You can also plan ahead and buy some before embarking, so long as the civilization that you embark from has bauxite.
If in limited supply on your map (and you are going to be playing with magma), be sure to keep your mason and various craftsdwarves away from what bauxite you do have until you can turn it into mechanisms; best forbid them until you are ready.
Bauxite is the only stone that contains rubies or sapphires, both found as small clusters.
While Bauxite is an aluminum ore in Real Life, the technology to extract aluminum from it does not exist in the game setting.